@article{403, keywords = {non-Palaiseau, paper}, author = {Matteo Gatti and Tokatly IV and Angel Rubio}, title = {Sodium: A Charge-Transfer Insulator at High Pressures}, abstract = {By first-principles methods we analyze the optical response of transparent dense sodium as a function of applied pressure. We discover an unusual kind of charge-transfer exciton that proceeds from the interstitial distribution of valence electrons. The absorption spectrum is strongly anisotropic, which, just at pressures above the metal-insulator transition, manifests as sodium being optically transparent in one direction but reflective in the other. This result provides key information about the crystal structure of transparent sodium, a new unconventional inorganic electride.}, year = {2010}, journal = {Physical Review Letters}, volume = {104}, pages = {216404}, month = {2010/May//}, publisher = {American Physical Society}, url = {http://dx.doi.org/10.1103/PhysRevLett.104.216404}, }