@article{387, keywords = {paper}, author = {Stefan Albrecht and G Onida and Lucia Reining}, title = {Ab initio calculation of the quasiparticle spectrum and excitonic effects in Li2O}, abstract = {We report an ab initio calculation of the binding energies and the nature of the excitonic states in the near-gap absorption spectrum of a real solid, Li2O. We calculate the ground-state properties using density-functional theory together with soft pseudopotentials. Applying Hedin\textquoterights GW approximation for the self-energy corrections to the band structure, we determine the minimal gap about 1 eV above the measured absorption onset. Finally, we obtain agreement with experiment by solving an effective two-particle Schrodinger equation for the electron-hole pairs.}, year = {1997}, journal = {Phys. Rev. B}, volume = {55}, number = {16}, pages = {10278-10281}, month = {APR 15}, publisher = {AMERICAN PHYSICAL SOC}, address = {ONE PHYSICS ELLIPSE, COLLEGE PK, MD 20740-3844 USA}, }